An investigation of the difference in enthalpy of combustions

Perspex screen draught proofing. This must then be placed inside the copper pot and a thermometer placed in the water, so it can adjust to the temperature of the room and the water.

An investigation of the difference in enthalpy of combustions

Determining the enthalpy change for a reaction of copper sulphate and zinc. To determine the enthalpy change for the single displacement reaction between zinc and copper sulphate: We take 1 pinch of zinc powder, put it into a container and determine its mass using digital scales: Although the precision of the instrument is to 0.

Zinc immediately reacts with the solution which becomes noticeably warmer. Being in powder form with minimum stirring it dissolves quickly.

At the beginning the solution has greenish colour. After zinc has dissolved, it loses almost all its colour and becomes colourless. Copper red-brown coloured precipitates at the bottom of the tube, having been displaced by zinc. Graph plotted from the data: The gradient shows the rate, at which the temperature decreases.

Very steep gradient at time when zinc is added indicates that the speed of reaction, I. Some of it could be ascribed to the uncertainties in measurement: The biggest contribution to the high experimental error is probably heat lost to surroundings.

The experimental value is much lower in magnitude than the actual value obtained, because much energy escaped as heat to the air. Reaction of displacement of copper by zinc in copper sulphate solution is exothermic, as heat is released upon reacting.

Chemistry Investigation: Alcohols

Zinc in powder reacts faster as the total surface area is higher. After reaching the peak temperature, the new solution starts to cool down, as it loses its heat to the surrounding environment. The best-fit line shows the theoretical temperature change in an ideal situation.

We can use it in calculations.

An investigation of the difference in enthalpy of combustions

However, in reality heat is lost to the surrounding, even whilst the reaction takes place. Zinc replaces copper in copper sulphate, because it is more reactive. Copper will precipitate, as it has very low solubility. The discrepancy is likely to be a combination of heat loss and error in determining the concentration of copper sulphate.

It is possible that the concentration of copper sulphate was lower and therefore less zinc reacted, releasing less energy than expected.- Comparing the Enthalpy Changes of Combustion of Different Alcohols Introduction In this investigation I will set out to find the differences in the enthalpies of combustion of 6 different alcohols.

These are methanol, ethanol, butanol, propanol, propanol and 2Methylpropanol. Chilled water should be used in the combustion portion of the investigation. Ice can be added to cool the water if needed.

However, unmelted ice should be removed from the water before using it . Use the information in the introduction to “INVESTIGATION ” on page of the textbook to arrange the provided reaction equations in order that they can be combined to create the reaction equation for the combustion of magnesium.

It can be taken further if used with post students who can calculate values for enthalpy changes of combustion, with subsequent discussion about heat losses and incomplete combustion.

The alcohols should be provided in labelled spirit burners ready to use. Chemistry Investigation – How does chain length affect: ∆Hcθ the products are at a lower energy level than the reactants and therefore the difference in energy (enthalpy) is always negative. The experiment of alcohol combustion is necessary, because it is otherwise impossible to derive enthalpy values.

They must be derived from the.

Enthalpies of Formation and Enthalpies of Combustion - The Student Room Tea light candle with metal cup and wick Watch glass Be sure you and the students wear properly fitting goggles.
Key Concepts Measure a known quantity of water into a flask and stand this on top of a tripod situated above a fuel source.
ChemTeam: Hess' Law - using standard enthalpies of formation There are also pointers to other sources of information.
Heat of Combustion of Methane But only a few know about the main differences between them. In combustion organic compounds are completely burnt and get oxidized to CO2 and water.

The quantitative study and measurement of heat and enthalpy changes is known as thermochemistry. The enthalpy change for a chemical reaction is the difference. q V ; the negative sign indicates that the reaction is exothermic, as all combustions are.) From the balanced reaction equation (C 6 H 5) 2 (s).

Heat of Combustion – Neutrium